Extended Flat Voltage Profile of Hard Carbon Synthesized Using a Two-Step Carbonization Approach as an Anode in Sodium Ion Batteries

Abstract

Hard carbon is a promising anode material for sodium ion batteries (NIBs). In this study, a two-step carbonization approach is developed to enhance the electrochemical performance of lignocellulose biomass-derived hard carbon. The first step comprises slow low-temperature pyrolysis of fir wood that produces an amorphous carbon in which hexagonal planes are embedded in the amorphous carbon region to some extent. The second step comprises high-temperature carbonization at 1300 °C, which yields a hard carbon with a high degree of graphitization, an increased layer-plane length, and a low micropore volume. Two-step carbonized hard carbon delivers a large reversible capacity of 276 mAh g‾¹ at 50 mA g‾¹ after 100 cycles and high rate capacities of 108 mAh g‾¹ at 1.0 A g‾¹ and 76.3 mAh g‾¹ at 2.5 A g‾¹. The low-voltage plateau capacity below 0.1 V is 194 mAh g‾¹. The results of these experiments indicate that the exceptional electrochemical performance of two-step carbonized hard carbon arises from the effective suppression of micropore formation and a good balance between the degree of graphitization and number of defect sites. High-voltage adsorption of Naþ ions in micropores inhibits Naþ-ion diffusion into the graphitic region of micropore-enriched hard carbon.